Patent · US Expired

Polymer having thiol end group

US4565854A · kind A · utility

29Cited by
2References
9Claims
0Family size

Assignee

Inventors

Key dates

Filing dateMar 22, 1984
Grant dateJan 21, 1986
Priority date
Expiry dateMar 22, 2004

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC08F293/00
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

The present invention relates to a polymer having a thiol group at one end of the molecule, which is obtained by subjecting the monomers capable of radical polymerization to radical polymerization in the presence of a thiolcarboxylic acid and then treating the resulting polymer with an alkali or acid; to a process for producing the same; and to a block copolymer based on the polymer having a thiol group at the end. The polymer having a thiol group at one end is difficult of forming disulfide linkages by oxidation and thus difficult of becoming insoluble. It is also a highly reactive material that will find wide use in varied application areas such as capture of heavy metals by forming a mercaptide. The block copolymer based on the polymer having a thiol group at the end is superior in compatibility and will find wide use in varied application areas such as surface size for paper, textile fiber finishing, additives for adhesives and paints, and binders for non woven textiles.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.