Preparation of hydrogenated silanes by redistribution of hydrosilanes
US4567286A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Sep 28, 1984 |
| Grant date | Jan 28, 1986 |
| Priority date | — |
| Expiry date | Sep 28, 2004 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC07F7/125
- WIPO fieldOrganic fine chemistry
- WIPO sectorChemistry
Abstract
Hydrogenosilanes are facilely prepared by redistribution, by reacting (1) a silane having the formula H.sub.m SiX.sub.4-m in which X is halogen or an alkoxy group and m is an integer equal to 0, 1, 2, or 3, with (2) an alkyl or aryl hydrogenosilane having the formula R.sub.n H.sub.p SiX'.sub.4-(n+p) in which X' is halogen or an alkoxy group, R is at least one alkyl or aryl group, which may be identical or different, and n and p, which may be identical or different, are integers equal to 1, 2 or 3, with the proviso that n+p.ltoreq.4, in the presence of (3) a catalytically effective amount of a catalyst system which comprises (i) at least one ionic inorganic salt having the formula M.sup.+ A.sup.- and (ii) a compound which complexes the M.sup.+ cation of said salt (i) and at least partially solubilizes and dissociates same in the medium of reaction.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.