Patent · US Expired

Flowthrough-type electrolytic cell

US4576706A · kind A · utility

5Cited by
2References
27Claims
0Family size

Assignee

Inventors

Key dates

Filing dateSep 5, 1984
Grant dateMar 18, 1986
Priority date
Expiry dateSep 5, 2004

Classification

  • Technology area (CPC G)Physics
  • CPC primaryG01N27/28
  • WIPO fieldMeasurement
  • WIPO sectorInstruments

Abstract

A sample leaving a separation column of liquid chromatograph is led to an electrolytic cell to obtain an electrolytic current corresponding to the amount of an assayed sample component. The electrolytic cell is divided into two compartments by an ion exchange pipe penetrating therethrough at the center. One compartment is a cylindrical working electrode chamber in the pipe, and the other compartment is a cylindrical chamber for a counterelectrode outside the pipe. A working electrode comprising a bundle of electroconductive carbon fibers is provided in the working electrode chamber, and preferably a swellable rod is inserted as a core into the working electrode. In the chamber for the counterelectrode, a cylindrical counterelectrode made of carbon fibers is provided to surround the outside surface of the ion exchange pipe. The inner diameter of the ion exchange pipe is substantially equal to the inner diameter of a tube for introducing the sample. The sample undergoes electrolysis reaction while the sample passes through the carbon fibers of the working electrode.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.