Patent · US Expired

Method for preparing cupric ion-free cuprous chloride

US4582579A · kind A · utility

2Cited by
5References
12Claims
0Family size

Assignee

Inventor

Key dates

Filing dateDec 24, 1984
Grant dateApr 15, 1986
Priority date
Expiry dateDec 24, 2004

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC01G3/05
  • WIPO fieldMaterials, metallurgy
  • WIPO sectorChemistry

Abstract

An improvement of the method for preparing cupric ion-free cuprous chloride powder in which copper metal is added to a highly acidified solution of cupric chloride to reduce the cupric ions to cuprous ions and oxidize the copper metal to cuprous ions. The improvement involves applying an electromotive force to the solution by immersing interconnected copper and platinum electrodes in the solution. The electromotive force is applied only after the reduction of cupric ions is near completion. The electromotive force is applied for a sufficient time to insure essentially complete reduction of cupric ions in the solution. Cuprous chloride is then separated from the cupric ion-free solution by evaporation and isolated by conventional techniques to provide an improved cuprous chloride powder product which is essentially free of cupric ions. The electromotive force is also applied during the evaporation of the acidified solution to prevent possible cupric ion formation. Removal of anion impurities from the cupric ion-free cuprous chloride powder is also disclosed.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.