Emulsions of crosslinked polydiorganosiloxanes
US4584341A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Jun 25, 1984 |
| Grant date | Apr 22, 1986 |
| Priority date | — |
| Expiry date | Jun 25, 2004 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC08J2383/04
- WIPO fieldMacromolecular chemistry, polymers
- WIPO sectorChemistry
Abstract
This invention is a method of producing a latex of crosslinked polydiorganosiloxane. The latex yields an elastomer upon removal of the water. The latex is prepared by homogenizing a mixture of hydroxyl endblocked polydiorganosiloxane, less than 75 millimoles of surface active anionic catalyst per kilogram of polydiorganosiloxane where said surface active anionic catalyst is dodecylbenzene sulfonic acid or hydrogen lauryl sulfate, and water to yield an oil-in-water emulsion. This emulsion is then admixed with from 0.5 to 15 parts by weight of an alkoxy silicon compound selected from a silane of the formula R.sub.a 'Si(OR.sup.3).sub.4-a where R' is a monovalent hydrocarbon radical of up to 12 carbon atoms, R.sup.3 is an alkyl radical of 1 to 6 carbon atoms, and a is 0 or 1, a partial hydrolyzate of the silane, or mixtures of silane and partial hydrolyzate. The resulting emulsion is maintained at a temperature of about 15.degree. to 30.degree. C. for at least 5 hours at a pH of less than 5 until a crosslinked polymer is formed, then the emulsion is admixed with sufficient base to raise the pH to greater than 7. The crosslinked polymer present in the latex is reinforced by adding great…
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.