Patent · US Expired

Method for making self-protecting carbon bodies

US4591514A · kind A · utility

4Cited by
4References
3Claims
0Family size

Assignee

Inventor

Key dates

Filing dateFeb 13, 1985
Grant dateMay 27, 1986
Priority date
Expiry dateFeb 13, 2005

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC04B41/89
  • WIPO fieldMaterials, metallurgy
  • WIPO sectorChemistry

Abstract

A method of forming a coated article is described. The article is composed of a carbon body having a thermochemically deposited coating which renders the body resistant to oxidation at high temperatures. A volatile gaseous halide of silicon is partially reduced to form a lower halide in a first reaction zone having a first pressure and separated from the body. The lower halide is flowed into a second reaction zone maintained at a pressure lower than the pressure in the first reaction zone. A gaseous alloying agent is introduced into the second reaction zone. The agent includes one or more elements selected from the group consisting of carbon, oxygen, aluminum, and nitrogen. As a consequence, a liquid phase intermediate compound is deposited on the substrate body which is thereafter thermochemically reacted to produce a coating of the silicon alloy. The coating has a non-columnar grain distribution with substantially equiaxial grains of an average diameter of less than one micron and forms a correspondingly fine crack mosaic upon stressing due to differences in thermal coefficients of expansion between the coating and the body. The lower halide and the alloying agent are controlled …

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.