Patent · US Expired

Process for the manufacture of optically active azetidinones

US4614614A · kind A · utility

28Cited by
2References
19Claims
0Family size

Assignee

Inventors

Key dates

Filing dateMar 22, 1984
Grant dateSep 30, 1986
Priority date
Expiry dateMar 22, 2004

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02P20/55
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

The present invention relates to an improved process for the manufacture of (3S)-3,4-trans-disubstituted azetidinones of the formula ##STR1## in which R.sub.1 represents hydrogen or lower alkyl, PA0 R.sub.2 represents hydrogen or a hydroxy-protecting group, PA0 Y represents the group --S(.dbd.O)--R.sub.3 or --S(.dbd.O).sub.2 --R.sub.3 wherein R.sub.3 represents an organic radical bonded to the sulphur atom by a carbon atom that is not bonded to hydrogen, or the group --C(.dbd.O)--O--R.sub.3 ' wherein R.sub.3 ' represents an organic radical bonded to the oxygen atom of the carboxy group by a carbon atom that is not bonded to hydrogen, or a carboxy-protecting group, and PA0 R.sub.4 represents hydrogen or an amino-protecting group R.sub.4 '. The process according to the invention is carried out under particularly favorable reaction conditions and yields compounds (I) in particularly high yields.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.