Organic nickel compounds, production and use thereof as catalysts in the polymerization of olefins

US4620021A · kind A · utility

Assignee

• BAYER HEALTHCARE LLC · DE

Inventors

• Karl-Heinz Aleksander Ostoja Starzewski · Bad Vilbel, DE
• Josef Witte · Cologne, DE
• Herbert Bartl · Odenthal, DE

Key dates

• Filing date: Sep 25, 1984
• Grant date: Oct 28, 1986
• Expiry date: Sep 25, 2004

Classification

• Technology area (CPC C): Chemistry; Metallurgy
• CPC primary: C08F10/00
• WIPO field: Organic fine chemistry
• WIPO sector: Chemistry

Abstract

Olefins such as ethylene can be polymerized with a catalyst which comprises nickel compounds obtained by reacting a nickel-(O) compound or a nickel compound which may be converted in situ into a nickel-(O) compound with an adduct or a mixture of a quinoid compound and a tertiary phosphine and with a compound corresponding to the following general formula: ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 independently represent C.sub.1 -C.sub.20 alkyl, C.sub.2 -C.sub.20 alkenyl, C.sub.6 -C.sub.12 aryl or C.sub.3 -C.sub.8 cycloalkyl optionally substituted by halogen, hydroxy, C.sub.1 -C.sub.20 alkoxy, nitro or C.sub.6 -C.sub.12 aryloxy; also C.sub.6 -C.sub.12 aryl-C.sub.1 -C.sub.20 alkyl, C.sub.6 -C.sub.12 aryl-C.sub.2 -C.sub.20 alkenyl, C.sub.1 -C.sub.20 alkyl-C.sub.6 -C.sub.12 aryl, C.sub.1 -C.sub.20 alkyl-C.sub.3 -C.sub.8 cycloalkyl and C.sub.6 -C.sub.12 aryl-C.sub.3 -C.sub.8 cycloalkyl, di-C.sub.1 -C.sub.4 alkylamino, optionally substituted phenoxy or alkoxy; R.sup.4, R.sup.5 and R.sup.6 represent hydrogen, silyl, halogen, cyano or R.sup.1 and PA0 X represents O, NR.sub.4 or ##STR2##