Patent · US Expired

Photographic products and processes

US4631344A · kind A · utility

1Cited by
6References
6Claims
0Family size

Assignee

Inventors

Key dates

Filing dateApr 29, 1985
Grant dateDec 23, 1986
Priority date
Expiry dateApr 29, 2005

Classification

  • Technology area (CPC G)Physics
  • CPC primaryG03C8/10
  • WIPO fieldBasic materials chemistry
  • WIPO sectorChemistry

Abstract

Photographic products and processes for the imagewise generation of a dye from a color shifted dye precursor of a preformed image dye, said precursor having at least one ##STR1## group, wherein R is hydrogen, alkyl, provided that the .alpha.-carbon does not have a hydrogen atom attached thereto, aryl such as phenyl or substituted phenyl, e.g. p-nitrophenyl, or heterocyclic such as pyridine; R.sub.1 -R.sub.6 are hydrogen, alkyl, preferably having from 1 to 6 carbon atoms, or aryl; n is 0 or 1; and T is a moiety containing a thiazolidin-2-yl group which upon silver-assisted cleavage of said thiazolidin-2-yl group results in the formation of a ##STR2## group, which may be protonated under the reaction conditions, followed by cleavage of said ##STR3## which cleavage is anchimerically assisted or accelerated by said ##STR4## to provide after protonation, an ##STR5## group in a dye chromophore. In a preferred embodiment the precursor is a substantially colorless compound.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.