Patent · US Expired

Dense anodes of lithium alloys for all solid batteries

US4652506A · kind A · utility

16Cited by
11References
24Claims
0Family size

Assignees

Inventors

Key dates

Filing dateMar 21, 1985
Grant dateMar 24, 1987
Priority date
Expiry dateMar 21, 2005

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02P70/50
  • WIPO fieldElectrical machinery, apparatus, energy
  • WIPO sectorElectrical engineering

Abstract

The disclosure describes an anode made of a thin metallic foil in discharged condition which is converted into a dense metallic alloy of an alkali metal during the first charge. The disclosure also describes an electrochemical rechargeable battery in discharged condition. The latter comprises an anode made of a thin metallic foil, such as aluminum, magnesium or tin, an electrolyte, for example a polymeric electrolyte, as well as a cathode based on an oxide, a sulfide or an halide, prepared in discharged condition and constituting a source of alkali metal preferably lithium. The cathode should be capable of freeing the alkali metal under a charge so that the latter is introduced into the metallic foil to form an alloy of the alkali metal and of at least a portion of the metal constituting the metallic sheet. To obtain the charged battery, it is merely sufficient to apply a charge during a certain period of time while the anode is being transformed into an alloy. Substantially improved properties during cycling.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.