Continuous inorganic fibers and process for production thereof
US4663229A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Feb 19, 1985 |
| Grant date | May 5, 1987 |
| Priority date | — |
| Expiry date | Feb 19, 2005 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY10T428/294
- WIPO fieldMaterials, metallurgy
- WIPO sectorChemistry
Abstract
Continuous inorganic fibers consisting substantially of Si, Zr and C and optionally of O, said fibers being composed of (1) an amorphous material consisting substantially of Si, Zr and C and optionally of O, or (2) an aggregate consisting substantially of ultrafine crystalline particles of .beta.-SiC, ZrC, a solid solution of .beta.-SiC and ZrC and ZrC.sub.1-x wherein O<x<1 and having a particle diameter of not more than 500 .ANG., in which amorphous SiO.sub.2 and ZrO.sub.2 sometimes exist in the neighborhood of these ultrafine crystalline particles, or (3) a mixture of said amorphous material (1) and said aggregate (2) of ultrafine crystalline particles. The aforesaid continuous inorganic fibers can be produced by the following steps: a first step of preparing a semi-inorganic block copolymer comprising polycarbosilane blocks having a main chain skeleton composed mainly of carbosilane units of the formula --Si--CH.sub.2 --, each silicon atom of said carbosilane units having bonded thereto a side-chain group selected from the class consisting of hydrogen, lower alkyl and phenyl, and zirconoxane units of the formula --Sr-O--; a second step of preparing a spinning dope of said semi-i…
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