AMS-1B crystalline borosilicate molecular sieve-based catalyst compositions and process for toluene alkylation
US4673767A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Nov 25, 1985 |
| Grant date | Jun 16, 1987 |
| Priority date | — |
| Expiry date | Nov 25, 2005 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02P20/52
- WIPO fieldOrganic fine chemistry
- WIPO sectorChemistry
Abstract
Described are catalyst compositions comprising a HAMS-1B crystalline borosilicate molecular sieve incorporated into an inorganic matrix, which have been impregnated with a magnesium compound or with both a phosphorus compound and a magnesium compound, said impregnated compositions having improved para-selectively for toluene alkylation. Such impregnated compositions, when used for the alkylation of toluene using methanol, methylether, ethylene, or propylene yield dialkylbenzene products containing a higher proportion of the para-isomer than corresponding unimpregnated borosilicate-based compositions. When toluene is alkylated with propylene using the impregnated catalyst compositions of this invention, a significant increase in para-selectivity among the cymene isomers is obtained at high total-cymene/n-propyltoluene ratios.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.