Patent · US Expired

Chemiluminescent sulfur detection apparatus and method

US4678756A · kind A · utility

17Cited by
14References
11Claims
0Family size

Assignee

Inventor

Key dates

Filing dateJun 9, 1982
Grant dateJul 7, 1987
Priority date
Expiry dateJun 9, 2002

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY10T436/188
  • WIPO fieldMeasurement
  • WIPO sectorInstruments

Abstract

In the illustrated and preferred embodiment of this disclosure, a chemiluminescent sulfur detector, both method and apparatus, for detecting bonded sulfur in compounds is disclosed. The illustrated and preferred embodiment, being provided with a discrete sample, passes the sample through a first furnace in the presence of a carrier of inert gas and is exposed to a suitable granulated metal oxide, such as copper oxide or vanadium pentoxide, resulting in oxidation of the sulfur compound. The sample is then passed through a second furnace comingled with elemental hydrogen, there being a conversion of sulfur oxides to hydrogen sulfide. The output of the second furnace is dried. The hydrogen sulfide, along with the inert carrier gas, is introduced into a reaction chamber and is mixed with ozone. A chemiluminescent reaction occurs in the chamber, and the resulting light emission is measured photoelectrically by either a photomultiplier tube or photodiode. The output from the photomultiplier tube is connected to a summing circuit, and the summation represents the measure of sulfur in the specimen. The reaction chamber is evacuated through an outlet system so that continuous processing of …

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.