Preparation of alpha-substituted .beta.-dicarbonyl, .beta.-cyano-carbonyl and .beta.-dicyano compounds
US4684743A · kind A · utility
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7Claims
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Key dates
| Filing date | Oct 1, 1985 |
| Grant date | Aug 4, 1987 |
| Priority date | — |
| Expiry date | Oct 1, 2005 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC07C49/403
- WIPO fieldOrganic fine chemistry
- WIPO sectorChemistry
Abstract
.beta.-Dicarbonyl, .beta.-cyanocarbonyl and .beta.-dicyano compounds I ##STR1## where R.sup.1 is an organic radical, X and Y are COOR.sup.2, --CO--R.sup.2 or --CN and R.sup.2 is an organic radical, are prepared from R.sup.1 --CHO (II) and X--CH.sub.2 --Y (III) by reaction in the presence of a condensation catalyst, hydrogen and a hydrogenation catalyst, using an oxide or phosphate of Mg, Al, Ti, Zn or a rare earth metal as the condensation catalyst.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.