Patent · US Expired

Process for manufacturing a composition of fatty acid esters useful as gas oil substitute motor fuel with hydrated ethyl alcohol and the resultant esters composition

US4695411A · kind A · utility

78Cited by
4References
17Claims
0Family size

Assignee

Inventors

Key dates

Filing dateFeb 18, 1986
Grant dateSep 22, 1987
Priority date
Expiry dateFeb 18, 2006

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02P30/20
  • WIPO fieldBasic materials chemistry
  • WIPO sectorChemistry

Abstract

The invention concerns a process for manufacturing a composition of fatty acid esters useful as gas oil substitute motor fuel, said composition containing at least one hydrated ethyl alcohol. The process comprises: PA0 (A) A first acid transesterification step in the presence of at least one aliphatic, linear or branched monoalcohol of 1 to 5 carbon atoms, consisting at least partly of hydrated ethyl alcohol containing 1 to 60% by weight of water, said step leading to the formation of a phase mainly containing ethyl esters after removal of the produced glycerol phase, PA0 (B) A second step wherein the initial free acidity or that formed during the first step in the phase containing the esters is decreased to a value at most equal to about 2%; and PA0 (C) A third step of basic transesterification of the phase resulting from step B, in the presence of at least one aliphatic, linear or branched monoalcohol of 1 to 5 carbon atoms, with the recovery of the so-formed ester composition. The composition of the invention can be used for combustion in Diesel engines.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.