Patent · US Expired

Highly active and highly selective aromatization catalyst

US4698322A · kind A · utility

12Cited by
10References
7Claims
0Family size

Assignee

Inventors

Key dates

Filing dateApr 17, 1985
Grant dateOct 6, 1987
Priority date
Expiry dateApr 17, 2005

Classification

  • Technology area (CPC B)Performing Operations; Transporting
  • CPC primaryB01J2229/42
  • WIPO fieldChemical engineering
  • WIPO sectorChemistry

Abstract

A highly selective zeolitic reforming catalyst is disclosed that contains a promoter selected from the group consisting of iron, cobalt, and titanium; and that has a platinum to promoter weight ratio of less than 10:1. In one embodiment a type L zeolite is formed by combining an aqueous solution of potassium hydroxide, aluminum hydroxide, and ferric nitrate with an aqueous solution of silica to form a thickening gel in a mother liquor; heating the thickening gel to form a type L zeolite; cooling the solution containing the type L zeolite; decanting the mother liquor from the solution; filtering the type L zeolite from the solution; washing the filtered type L zeolite so that the pH of the wash is about 101/2; and drying the washed type L zeolite. The catalyst is formed by adding platinum to the dried type L zeolite by pore fill impregnation with an aqueous solution of Pt(NH.sub.3).sub.4 (NO.sub.3).sub.2 to form a catalyst; drying the catalyst and calcining the catalyst.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.