Patent · US Expired

Microelectrochemical devices

US4717673A · kind A · utility

394Cited by
11References
19Claims
0Family size

Assignee

Inventors

Key dates

Filing dateNov 19, 1985
Grant dateJan 5, 1988
Priority date
Expiry dateNov 19, 2005

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY10T436/209163
  • WIPO fieldMeasurement
  • WIPO sectorInstruments

Abstract

Very stable, polymer-based electrochemical devices, formed by polymerization of thiophene or a derivative such as 3-methylthiophene which is durable in an aqueous electrolyte over a wide pH range, which respond rapidly to chemical or electrical signals, are disclosed. In one embodiment, the device functions as an extremely sensitive sensor which measures changes in chemical concentration or pH. For example, a poly-3-methylthiophene-based device is sensitive to as little as 8.times.10.sup.-16 moles of an oxidant which reversibly interacts with the polymer, including gas phase oxidants such as I.sub.2. In a variation of the polymer-based device, a catalyst such as a noble metal or an enzyme, is dispersed on or within the conducting polymer matrix so that the device is responsive to chemicals such as H.sub.2 and O.sub.2 which the polymer would otherwise respond very slowly to. In a second embodiment, a polymer-based electrochromic device consists of polymer-coated microelectrodes which are individually addressed. Very high resolution is achieved by separating the microelectrodes by distances on the order of 10,000 Angstroms. In still another embodiment, the polymer-based device functi…

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.