Patent · US Expired

Process for the preparation of carbamates, thiocarbamates and ureas

US4725680A · kind A · utility

8Cited by
1References
14Claims
0Family size

Assignee

Inventors

Key dates

Filing dateFeb 14, 1985
Grant dateFeb 16, 1988
Priority date
Expiry dateFeb 14, 2005

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07F7/081
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

The invention relates to a process for preparing carbamic acid derivatives of formula: ##STR1## in which R.sup.1 or R.sup.2 denotes a hydrogen atom or a substituted or unsubstituted, saturated or unsaturated aliphatic, cycloaliphatic or heterocyclic radical, or R.sup.1 and R.sup.2 together form a ring, and Y denotes OR, SR, ##STR2## groups, R being a substituted or unsubstituted, saturated or unsaturated aliphatic or cycloaliphatic radical, or a substituted or unsubstituted aromatic radical, R.sup.3 and R.sup.4 denote a hydrogen atom or an aliphatic, cycloaliphatic, araliphatic, aromatic or heterocyclic radical or together form a ring, and R.sup.6 and R.sup.7 denote a saturated or unsaturated, substituted or unsubstituted aliphatic or cycloaliphatic radical, a hydrogen atom, an alkylthio radical or an alkyloxy radical. According to the process, a compound of formula ##STR3## is reacted with an .alpha.-halogenated derivative of formula ##STR4## at a temperature of -5.degree. to 150.degree. C. in the presence of an acceptor for hydrohalic acid. The carbamates, thiocarbamates or ureas obtained are very useful, especially as pesticides.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.