Patent · US Expired

Process for producing micro-porous membrane of ultra-high-molecular-weight alpha-olefin polymer, micro-porous membranes and process for producing film of ultra-high-molecular-weight alpha-olefin polymer

US4734196A · kind A · utility

36Cited by
3References
6Claims
0Family size

Assignee

Inventors

Key dates

Filing dateFeb 24, 1986
Grant dateMar 29, 1988
Priority date
Expiry dateFeb 24, 2006

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC08J2323/02
  • WIPO fieldChemical engineering
  • WIPO sectorChemistry

Abstract

A micro-porous membrane of ultra-high-molecular-weight alpha-olefin polymer having a weight-average molecular weight greater than 5.times.10.sup.5, the micro-porous membrane having through holes 0.01 to 1 micrometer in average pore size, with a void ratio from 30 to 90% and being oriented such that the linear draw ratio in one axis is greater than two and the areal draw ratio is greater than ten. The micro-porous membrane is obtained by forming a gel-like object from a solution of an alpha-olefin polymer having a weight-average molecular weight greater than 5.times.10.sup.5, removing at least 10 wt % of the solvent contained in the gel-like object so that the gel-like object contains 10 to 90 wt % of alpa-olefin polymer, orientating the gel-like object at a temperature lower than that which is 10.degree. C. above the melting point of the alpa-olefin polymer, and removing the residual solvent from the orientated product. A film is produced from the orientated product by pressing the orientated product at a temperature lower than that of the melting point of the alpha-olefin polymer.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.