Organopolysiloxane composition curable by hydrosilylation containing platinum/triene complexes
US4741966A · kind A · utility
Assignee
Inventor
Key dates
| Filing date | Nov 20, 1986 |
| Grant date | May 3, 1988 |
| Priority date | — |
| Expiry date | Nov 20, 2006 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY10T428/31663
- WIPO fieldMacromolecular chemistry, polymers
- WIPO sectorChemistry
Abstract
Novel platinum/olefin complexes, useful for the hydrosilylation curing catalysis of hardenable organopolysiloxane compositions, are facilely prepared by reacting a platinum halide with at least one alkali or alkaline earth metal carbonate or bicarbonate in the presence of an aliphatic triene ligand having the general formula: ##STR1## wherein R.sub.1 is a linear or branched chain alkyl radical having from 1 to 6 carbon atoms, and R.sub.2 is R.sub.1 or a linear or branched chain alkenyl radical having from 2 to 16 carbon atoms and at least one site of ethylenic unsaturation, and said complex having a ratio, in gram-atoms of halogen to gram-atoms of platinum, ranging from virtually 0 to 4.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.