Bismuth/carboxylic acid catalysts for preparing elastomers
US4742090A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Mar 31, 1986 |
| Grant date | May 3, 1988 |
| Priority date | — |
| Expiry date | Mar 31, 2006 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC08G2120/00
- WIPO fieldOrganic fine chemistry
- WIPO sectorChemistry
Abstract
This invention is a polyurethane-urea elastomer which is the reaction product of a reaction mixture comprising (1) a liquid active hydrogen-containing composition which comprises a relatively high equivalent weight active hydrogen-containing compound, and an amine-terminated, relatively low equivalent weight compound, (2) a polyisocyanate which is present in an amount to provide about 0.8 to about 1.5 isocyanate groups per active hydrogen-containing group present in the mixture, and (3) a catalytically effective amount of a bismuth carboxylate catalyst. With the use of the bismuth carboxylate catalyst, excellent pot-life, yet rapid cures are achieved. In addition the so-called "green strength" of the elastomer, i.e., its physical strength at the time of its removal from the mold, is improved with the practice of this invention. Further, the post-cured elastomer exhibits excellent properties.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.