Condensation polymers containing methine ultraviolet radiation-absorbing residues and shaped articles produced therefrom
US4749773A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Jul 27, 1987 |
| Grant date | Jun 7, 1988 |
| Priority date | — |
| Expiry date | Jul 27, 2007 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC08G64/045
- WIPO fieldMacromolecular chemistry, polymers
- WIPO sectorChemistry
Abstract
A composition useful for molding into articles such as food containers, soft drink bottles, cured structural plastics and the like, comprising molding grade linear or unsaturated polyester or polycarbonate having reacted or copolymerized therein a total of from 100 to about 800 ppm, of the residue of one or a mixture of methine reactants of the formula ##STR1## wherein R.sup.1 is hydrogen or an unsubstituted or substituted alkyl, alkenyl, cycloalkyl or aryl radical; PA1 A.sup.1 is an unsubstituted or substituted phenylene radical; PA1 A.sup.2 is an unsubstituted or substituted 1,4-phenylene radical; PA1 R.sup.2 is hydrogen or an unsubstituted or substituted alkyl, cycloalkyl or aryl radical; PA1 R.sup.3 is cyano or ##STR2## and R.sup.4 is one of the substituents which R.sup.3 can represent or an unsubstituted or substituted carbamoyl, alkanoyl, aroyl, alkylsulfonyl, arylsulfonyl, aryl or aromatic heterocyclic radicals. The methine residues are present in the polymer as an integral part of the polymer chain and absorb ultraviolet radiation in the range of about 250 to about 390 nm. The residues are non-extractable from the polymer and stable at the conditions at which the polymers a…
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.