Electrochromic polymer comprising N,N'-diphenyl-N,N'-diphenylene-phenylene diamine units
US4786715A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | May 27, 1987 |
| Grant date | Nov 22, 1988 |
| Priority date | — |
| Expiry date | May 27, 2007 |
Classification
- Technology area (CPC H)Electricity
- CPC primaryH01B1/128
- WIPO fieldMacromolecular chemistry, polymers
- WIPO sectorChemistry
Abstract
The disclosure relates to a novel polymer which is made up of repeating units of N,N,N'N'-tetrapheny-p-phenylenediamine. This polymer is thermoplastic and is soluble in industrially usable organic solvents. The polymer acquires high conductivity by doping with an electron acceptor. The polymer becomes insoluble in organic solvents when it is once doped with an electron acceptor and then dedoped, so that the polymer can be used as an active electrode material in electrolytic devices using an organic solvent. The polymer has electrochromic properties and undergoes two-stage oxidation and two-stage reduction to assume three differently stable states. The polymer exhibits pale yellow color in its reduced state, green color in the first-stage oxidized state and dark blue color in the second-stage oxidized state.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.