Process of reducing higher metal oxides to lower metal oxides

US4789580A · kind A · utility

Assignee

• Metallgesellschaft AG · DE

Inventors

• Martin Hirsch · Friedrichsdorf, DE
• Hermann Lommert · Neu-Isenburg, DE
• Harry Serbent · Hanau, DE

Key dates

• Filing date: Nov 13, 1986
• Grant date: Dec 6, 1988
• Expiry date: Nov 13, 2006

Classification

• Technology area (CPC Y): Emerging Cross-Sectional Technologies
• CPC primary: Y10S423/16
• WIPO field: Materials, metallurgy
• WIPO sector: Chemistry

Abstract

Disclosed is a process to effect a reduction to a desired, constant degree as exactly as possible and to achieve a low surplus of carbon. The reduction by treatment with carbonaceous reducing agents is effected in such a manner that fine-grained solids, which contain higher metal oxides, are calcined at 800.degree. to 1100.degree. C. with hot gases in which the solids are suspended. The calcined solids are reduced at a temperature in the range of from 800.degree. to 1100.degree. C. to form low metal oxides in a stationary fluidized bed, which is supplied with carbonaceous reducing agents and oxygen-containing gases. The carbonaceous reducing agents are supplied to the stationary fluidized bed at such a rate so as to reduce the higher metal oxides to low metal oxides, while maintaining the reduction temperature in the stationary fluidized bed and insuring that the discharged matter has the desired carbon content. The stationary fluidized bed exhaust gas is supplied as secondary gas to the calcining step, and fuel is supplied to the calcining step at a rate such that the total of the heat generated by the combustion of the fuel and of the heat suplied by the exhaust gas provides the …