Process for metallating nonconjugated diene-containing ethylene polymers and graft polymers prepared therefrom
US4794145A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Oct 16, 1987 |
| Grant date | Dec 27, 1988 |
| Priority date | — |
| Expiry date | Oct 16, 2007 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC08F8/42
- WIPO fieldMacromolecular chemistry, polymers
- WIPO sectorChemistry
Abstract
A process is provided for metallating ethylene polymers which have polymerized therein a minor amount of nonconjugated diene. Metallation is accomplished with a blend of three metallating reagents: (a) an alkyllithium compound; (b) a potassium alkoxide; and (c) a chelating tertiary diamine. The metallated polymers so prepared may be reacted with one or more anionically polymerizable monomers to form graft polymers or with a reagent such as carbon dioxide to form a functionalized polymer. When the anionically polymerizable monomer has two or more polymerizable sites, the metallated polymer is reacted with a modifying compound such as alpha-methylstyrene before it is reacted with the monomer(s). Certain of the graft polymers behave as thermoplastic elastomers whereas others are thermoplastic. The blend of metallating reagents may be used with any polymer having partial or complete unsaturation.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.