Hypofluorites and bis-hypofluorites, and process for preparing same
US4801409A · kind A · utility
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9Claims
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Key dates
| Filing date | Sep 8, 1987 |
| Grant date | Jan 31, 1989 |
| Priority date | — |
| Expiry date | Sep 8, 2007 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC07C309/00
- WIPO fieldOrganic fine chemistry
- WIPO sectorChemistry
Abstract
Mono- and bis-hypofluorites respectively of formula: FO.sub.2 S--R.sub.f --CF.sub.2 OF and FOCF.sub.2 --R'.sub.f --CF.sub.2 OF wherein R.sub.f is perfluoroalkylene or perfluorochloroalkylene and R'.sub.f is a perfluoroalkylene or perfluorooxyalkylene, and process for preparing them, which is conducted continuously, at a temperature from 0.degree. to 60.degree. C. and comprises starting from the respective acyl fluorides ##STR1## by reaction of fluorine in the gas phase in the presence of a catalyst consisting of K, Rb, Cs or Ba fluoride, preferably supported on a metal material.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.