Patent · US Expired

Process for the preparation of aryloxyacetic acid

US4804777A · kind A · utility

5Cited by
1References
12Claims
0Family size

Assignee

Inventors

Key dates

Filing dateOct 9, 1987
Grant dateFeb 14, 1989
Priority date
Expiry dateOct 9, 2007

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07C51/235
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

Process for the preparation of an aryloxyacetic acid by oxidation of aryloxyethanol of the formula: ##STR1## wherein m represents 1 or 2, PA1 n represents the numeral which results from the difference between 6 and m and R either individually or independently of one another represents hydrogen, alkyl, cycloalky, aryl, aralkyl, alkoxy, cycloalkoxy, aryloxy, halogen, alkylcarbonyl, arylcarbonyl, carboxyl or nitro, or represents a benzene ring fused to the phenyl ring, in an aqueous alkaline reaction medium at a temperature in the range of 0.degree. C. to the boiling point of the reaction medium in the presence of a catalytic amount of a catalyst comprised of palladium, silver and optionally antimony, and carbon to form the corresponding alkali metal ester and contacting the alkali metal with a mineral acid.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.