Polyethers obtainable by reacting alkylolated bis-(4-hydroxyphenyl)-methanes with polyalkylene oxides, and their use as oil demulsifiers
US4814394A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Apr 28, 1987 |
| Grant date | Mar 21, 1989 |
| Priority date | — |
| Expiry date | Apr 28, 2007 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC08G65/34
- WIPO fieldMacromolecular chemistry, polymers
- WIPO sectorChemistry
Abstract
Polyethers with are suitable as oil demulsifiers are obtainable by reacting PA0 (A) a polyalkylene oxide obtained from ethylene oxide and propylene oxide and containing in total from 5 to 200 alkylene oxide units with PA0 (B) an alkylolation product of a low molecular weight aldehyde and a bis-(4-hydroxyphenyl)-methane of the general formula II ##STR1## wherein R.sup.1 and R.sup.2 may be identical or different and are each hydrogen, low molecular weight alkyl, phenyl, carboxyl or low molecular weight alkoxycarbonyl, the molar reaction ratio of the compound of the formula II to the alkylolating aldehyde being from 1:1 to 1:4, at from 100.degree. to 180.degree. C. in the presence of an acidic catalyst with removal of the water of reaction, the weight ratio of A to B being from 5:1 to 1:3.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.