Photoreactive lenses with adamantane spiro compounds
US4818096A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Jun 17, 1987 |
| Grant date | Apr 4, 1989 |
| Priority date | — |
| Expiry date | Jun 17, 2007 |
Classification
- Technology area (CPC G)Physics
- CPC primaryG02B5/23
- WIPO fieldOrganic fine chemistry
- WIPO sectorChemistry
Abstract
Photoreactive plastics lenses are disclosed which are coated or impregnated with an adamantane 2-spiro-benzo or naphthopyran and with a blue coloring photochromic benzo- or naphthopyran having a nitrogen containing substituent in the 2-position in the pyran ring. The lenses darken in sunlight and fade rapidly at ambient temperatures in the dark or in white light which does not contain a U.V. component. The combination of the yellow/orange coloring adamantane 2-spiro pyran compound with the purple/blue coloring pyran gives a desired brown/grey coloration in the sunlight-darkened lens. The invention includes novel blue-coloring pyran compounds in which the nitrogen-containing substituent in the 2-position is a phenyl group having an amino or substituted amino or nitrogen-containing heterocyclic substituent in the ortho- or para-position of the phenyl group. The basic chromene structure and the suffix N will be used to distinguish the blue-coloring pyran compounds having a nitrogen-containing substituent, namely: ##STR1##
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.