UV curable coatings containing oxalanilide stabilizers, method of curing, and coated substrates therefrom
US4833038A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Mar 14, 1988 |
| Grant date | May 23, 1989 |
| Priority date | — |
| Expiry date | Mar 14, 2008 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY10T428/31699
- WIPO fieldBasic materials chemistry
- WIPO sectorChemistry
Abstract
A metallized plastic substrate having directly adhered to the metallized surface thereof, a transparent, cross-linked film from a coating composition comprises: (A) from 4 to 10 percent of an oxalanilide ultraviolet light (UV) stabilizer dissolved in the coating composition, the UV stabilizer corresonding to the formula ##STR1## in which R is C.sub.6-22 alkyl or C.sub.6-22 alkoxy, R.sub.1 and R.sub.2 are independently hydrogen, C.sub.1-8 alkyl, C.sub.1-12 alkoxy, C.sub.1-12 alkylthio, phenoxy or phenylthio, provided that R.sub.1 and R.sub.2 may not both be selected from alkylthio, phenoxy and phenylthio, and R.sub.3 is hydrogen or C.sub.1-8 alkyl; (B) from 20 to 80 percent of a radiation sensitive monomer having at least two addition polymerizable unsaturated bonds; (C) from 0.1 to 5.0 percent of a photopolymerization initiator; and (D) from 80 to 20 percent of an acrylic addition polymer having at least one amino group and having a number average molecular weight of about 8,000-70,000, the addition polymer being derived from a mixture of copolymerizable ethylenically unsaturated monomers containing a monomeric ethylenically unsaturated amine. The percentages of components (A), (B)…
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.