Patent · US Expired

Ethylene furnace antifoulants

US4842716A · kind A · utility

25Cited by
14References
17Claims
0Family size

Assignee

Inventors

Key dates

Filing dateAug 13, 1987
Grant dateJun 27, 1989
Priority date
Expiry dateAug 13, 2007

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY10S585/95
  • WIPO fieldBasic materials chemistry
  • WIPO sectorChemistry

Abstract

An improved method for reducing fouling and corrosion of ethylene cracking furnaces petroleum feedstocks, the improvement comprising treating the petroleum feed stock with at least 10 ppm of a combination of a phosphorous antifoulant compound and a filming inhibitor. The antifoulant compound is chosen from the group consisting of phosphite esters, phosphate esters, thiophosphite esters, thiophosphate esters and mixtures thereof, said esters being characterized by the formulas ##STR1## where X equals S or O, and R.sub.1, R.sub.2, and R.sub.3, are each independently selected from the group consisting of hydrogen, water soluble amine, alkyl, aryl, alkaryl, cycloalkyl, alkenyl, and aralkyl group provided that in at least one and not more than two of each R.sub.1, R.sub.2, and R.sub.3 are water soluble amines having partition coefficients greater than 1.0 mixed with a filming amount of at least 2-20 ppm imidazoline filming inhibitor prepared preferably from naphthenic or fatty acids and poly amines.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.