Patent · US Expired

Polyvinyl chloride resin composition

US4857592A · kind A · utility

4Cited by
1References
4Claims
0Family size

Assignee

Inventors

Key dates

Filing dateFeb 11, 1988
Grant dateAug 15, 1989
Priority date
Expiry dateFeb 11, 2008

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC08L51/00
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

A polyvinyl chloride resin composition comprises 3-30 wt. % of a graft copolymer and 97-70 wt. % of a polyvinyl chloride resin and has highly-balanced properties between impact resistance, transparency and stress-whitening resistance and excellent processing characteristics. The graft copolymer is obtained by graft-polymerizing, in the presence of a latex containing greater than 75 but not exceeding 85 parts by weight of a rubbery butadiene-styrene copolymer formed of 65-85 wt. % of butadiene, 15-35 wt. % of styrene and 0-3 wt. % of crosslinkable monomer, (i) 5-24 parts by weight of a first monomer mixture as a first-stage component, said first monomer mixture being composed of 70-97 wt. % of methyl methacrylate and 30-3 wt. % of an alkyl acrylate whose alkyl group has 1-8 carbon atoms; and then (ii) 3-21 parts by weight of a second monomer mixture as a second-stage component, said second monomer mixture being composed of 97-100 wt % of styrene and 0-3 wt. % of crosslinkable monomer. The sum of the first and second monomer mixtures and the rubbery butadiene-styrene copolymer is 100 parts by weight. The monomers grafted in the first stage amount to 30-80 wt. % of the sum of the graf…

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.