Application of catalysts containing rhodium
US4863639A · kind A · utility
3Cited by
3References
4Claims
0Family size
Assignee
Inventors
Key dates
| Filing date | May 15, 1987 |
| Grant date | Sep 5, 1989 |
| Priority date | — |
| Expiry date | May 15, 2007 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC07C237/26
- WIPO fieldOrganic fine chemistry
- WIPO sectorChemistry
Abstract
The present invention refers to the compounds (.mu.-hydrazine-N.sup.1 :N.sup.2)-bis[bis(triphenylphosphine)-chlororhodium (I)] and di(.mu.-hydrazine-N.sup.1 :N.sup.2)-bis[bis(triphenylphosphine)rhodium (I)] dichloride, which are homogenous hydrogenation catalysts and their application in the hydrogenation of the exocyclic methylene group of acid addition salts of 6-demethyl-6-deoxy-6-methylene-5-hydroxytetracycline (methacycline) to prepare .alpha.-6-deoxy-5-hydroxytetracycline (doxycycline).
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.