Separation of actinides from lanthanides
US4867951A · kind A · utility
11Cited by
6References
2Claims
0Family size
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Key dates
| Filing date | Mar 31, 1988 |
| Grant date | Sep 19, 1989 |
| Priority date | — |
| Expiry date | Mar 31, 2008 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02P10/20
- WIPO fieldMaterials, metallurgy
- WIPO sectorChemistry
Abstract
An organic extracting solution and an extraction method useful for separating elements of the actinide series of the periodic table from elements of the lanthanide series, where both are in trivalent form. The extracting solution consists of a primary ligand and a secondary ligand, preferably in an organic solvent. The primary ligand is a substituted monothio-1,3-dicarbonyl, which includes a substituted 4-acyl-2-pyrazolin-5-thione, such as 4-benzoyl-2,4-dihydro-5-methyl-2-phenyl-3H-pyrazol-3-thione (BMPPT). The secondary ligand is a substituted phosphine oxide, such as trioctylphosphine oxide (TOPO).
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.