Zeolite catalyst composition and synthesis method
US4868146A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Aug 25, 1988 |
| Grant date | Sep 19, 1989 |
| Priority date | — |
| Expiry date | Aug 25, 2008 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY02P20/584
- WIPO fieldChemical engineering
- WIPO sectorChemistry
Abstract
A surface-inactive shape selective metallosilicate catalyst, useful for the conversion of lower molecular weight olefins to liquid hydrocarbons such as gasoline, distillate, and high viscosity lube oils, is prepared by forming a silica shell on a medium pore metallosilicate core by crystallizing silica in the presence of fluoride ion onto the surface of the core. A novel catalyst composition is provided comprising an inner core portion and an outer portion disposed as a porous shell around the inner portion, wherein the inner portion consists essentially of metallosilicate zeolite having a medium pore structure, such as ZSM-5 or ZSM-23, and the outer portion comprising a fluoride-containing crystalline shell consisting essentially of silica substantially free of acid sites and having substantially the same crystalline structure as the inner core portion.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.