Patent · US Expired

Process for separating dichlorodiphenylsulfone isomers

US4876390A · kind A · utility

5Cited by
12References
9Claims
0Family size

Assignee

Inventor

Key dates

Filing dateAug 19, 1988
Grant dateOct 24, 1989
Priority date
Expiry dateAug 19, 2008

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07C315/06
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

A process for the liquid phase adsorptive separation of 4,4'-dichlorodiphenylsulfone (4,4'-DCDPS) from crystallization residue feed mixture also containing other DCDPS isomers. The feed is contacted with an X or Y type zeolite, substituted with a cation of a Group IA or IIA metal or ammonium. The other isomers are selectively adsorbed to the substantial exclusion of 4,4'-DCDPS. The 4,4'-DCDPS is recovered in high purity by fractionating the raffinate to recover the desorbent, aliphatic alcohols having 4-8 carbon atoms either used alone or diluted with an aromatic compound.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.