Patent · US Expired

Hydrocarbon conversion process for selectively making middle distillates

US4879019A · kind A · utility

21Cited by
31References
28Claims
0Family size

Assignee

Inventor

Key dates

Filing dateApr 4, 1988
Grant dateNov 7, 1989
Priority date
Expiry dateApr 4, 2008

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC10G47/16
  • WIPO fieldBasic materials chemistry
  • WIPO sectorChemistry

Abstract

A hydrocarbon conversion catalyst useful for converting hydrocarbon feeds to midbarrel products is prepared by extruding a mixture of a porous, inorganic refractory oxide component and a crystalline aluminosilicate zeolite having cracking activity to form extrudates which are broken into particles normally ranging in length between 1/16 and 1/2 inch. The extruded particles are then calcined in the presence of added steam at a water vapor partial pressure greater than about 2.0 p.s.i.a., preferably greater than about 5.0 p.s.i.a. The calcination step is carried out in the presence of sufficient added steam for a sufficient amount of time at a sufficient temperature to convert the crystalline aluminosilicate zeolite in the extrudates into an ultrahydrophobic zeolite having a unit cell size between about 24.20 and about 24.45 Angstroms and a sorptive capacity for water vapor less than about 5 weight percent of the zeolite at 25.degree. C. and a p/p.degree. value of 0.10.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.