Patent · US Expired

Preparation of mixtures of butanediols

US4879420A · kind A · utility

9Cited by
2References
18Claims
0Family size

Assignee

Inventor

Key dates

Filing dateMay 6, 1988
Grant dateNov 7, 1989
Priority date
Expiry dateMay 6, 2008

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC07C45/59
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

Process for preparing 2-alkyl-1,4-butanediols and mixtures with 1,4-butanediol which comprises bringing together, at an initial alkaline pH, and at a temperature and pressure suitable for reaction, a mixture of 4-hydroxybutyraldehyde and/or its cyclic acetal, 2-hydroxytetrahydrofuran, hydrogen, an unsubstituted aliphatic aldehyde, especially formaldehyde, and a hydrogenation catalyst. Also processes for preparing mixtures of tetrahydrofuran and 3-alkyltetrahydrofuran from the diol mixtures, and copolymers from the tetrahydrofuran mixtures.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.