Macroporous polymeric membranes for the separation of polymers and a method of their application
US4889632A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Dec 7, 1988 |
| Grant date | Dec 26, 1989 |
| Priority date | — |
| Expiry date | Dec 7, 2008 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY10S264/62
- WIPO fieldChemical engineering
- WIPO sectorChemistry
Abstract
An object of the invention are macroporous polymeric membranes, suitable above all for the separation of polymers, which consist of the copolymer of a monovinyl monomer, selected from the group comprising acrylates, methacrylates, vinylpyridine, N-vinylpyrrolidone, vinyl acetate, and hydroxystyrene, with a divinyl monomer, selected from the group comprising alkylene and hydroxyalkylene diacrylates and dimethacrylates, divinylbenzene, and divinylpyridine, at the ratio of monomers of both types ranging from 5:95 to 95:5 wt.%. The membranes are formed from polymeric globular entities which have the size 0.05 to 0.05 .mu.m and are interconnected by covalent bonds, whereas communicating voids - pores occur between the globuli. The total thickness of membranes is 0.2 to 15 mm and their specific surface area, which is measurable also in the dry state, may attain 400 m.sup.2 /g. Glycidyl methacrylate is advantageously used as the monovinyl monomer in the amount 5-80 vol.% related to the total volume of monomers. Ethylene dimethacrylate is advantageously used in the amount 20-95 vol.% related to the volume of monomers as the divinyl monomer. The membranes contain on their inner surface cova…
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.