Process for the preparation of vinyl acetate
US4902823A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Feb 7, 1989 |
| Grant date | Feb 20, 1990 |
| Priority date | — |
| Expiry date | Feb 7, 2009 |
Classification
- Technology area (CPC B)Performing Operations; Transporting
- CPC primaryB01J35/63
- WIPO fieldChemical engineering
- WIPO sectorChemistry
Abstract
The invention relates to a process for the preparation of vinyl acetate in the gas phase from ethylene, acetic acid and oxygen or oxygen-containing gases on a catalyst which contains palladium and/or compounds thereof and if appropriate additionally gold and/or gold compounds and, as activators, alkali metal compounds and if appropriate additionally cadmium compounds, on a support. The support consists of cylindrical particles with curved front faces. The support material is aerogenic SiO.sub.2 or an aerogenic SiO.sub.2 -Al.sub.2 O.sub.3 mixture having a surface area of 50-250 m.sup.2 /g and a pore volume of 0.4-1.2 ml/g, which is formed to the extent of at least 50% by pores having a diameter of 50-200 .ANG..
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.