Patent · US Expired

Polysiloxane bound photosensitizer for producing singlet oxygen

US4921589A · kind A · utility

37Cited by
12References
28Claims
0Family size

Assignee

Inventors

Key dates

Filing dateDec 20, 1988
Grant dateMay 1, 1990
Priority date
Expiry dateDec 20, 2008

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY10S522/904
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

This invention relates to a photosensitizer which is bound to a polysiloxane polymer, a method of preparing the bound photosensitizer and a process for using the bound photosensitizer. The photosensitizers which may be used in the invention include rose bengal, rhodamine B, acridine orange, methylene blue and zinc phthalocyanine. The photosensitizer is attached to the polysiloxane by reacting a hydroxyl or vinyl group on the photosensitizer with a hydrogen on the polyhydrosiloxane, thereby binding the photosensitizer into the polymer network. Finally, the bound photosensitizer may be used to oxidize undesirable oxidizable compounds present in a hydrocarbon or aqueous fraction. One specific example is the sweetening of kerosene which involves oxidizing the mercaptans contained in the kerosene.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.