Patent · US Expired

Method and apparatus for minimizing polymer agglomerate or lump formation in a gas-phase polypropylene polymerization reactor

US4921919A · kind A · utility

12Cited by
6References
3Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJun 3, 1988
Grant dateMay 1, 1990
Priority date
Expiry dateJun 3, 2008

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY10S526/919
  • WIPO fieldChemical engineering
  • WIPO sectorChemistry

Abstract

The process and the system are used for carrying out the quench-cooled, vapor-phase polymerization of olefin monomer in a horizontally disposed reactor vessel which comprises contacting olefin monomer, or a mixture of olefin monomers, with a polymerization catalyst system in the presence of hydrogen in the reactor vessel to form a polymer product. The improvement comprises introducing a titanium-containing catalyst component of the catalyst system into the top side of the reactor vessel at a point adjacent to the upstream end of the reactor vessel and introducing a cocatalyst plus modifer component of the catalyst system into the top side of the reactor vessel at a distance, downstream of the point of introduction of the titanium-containing catalyst component, which is equal to 25% of the inside diameter of the reactor vessel.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.