Patent · US Expired

Synthesis of caprolactam

US4927924A · kind A · utility

6Cited by
4References
16Claims
0Family size

Assignee

Inventors

Key dates

Filing dateApr 14, 1989
Grant dateMay 22, 1990
Priority date
Expiry dateApr 14, 2009

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02P20/52
  • WIPO fieldChemical engineering
  • WIPO sectorChemistry

Abstract

A process is provided for catalytically converting cyclohexanone oxime to epsilon caprolactam. The conversion is characterized by exceptionally high selectivity and reduced rate of catalyst aging, even at single pass conversion above 90 percent. The conversion catalyst is a medium pore size crystalline zeolite exemplified by ZSM-5 which has low acid activity. Recycling unconverted oxime provides excellent ultimate yield of caprolactam.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.