Stabilized pigmented polypropylene fiber resistant to gas fade
US4929653A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Jul 13, 1987 |
| Grant date | May 29, 1990 |
| Priority date | — |
| Expiry date | Jul 13, 2007 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY10T428/2971
- WIPO fieldMacromolecular chemistry, polymers
- WIPO sectorChemistry
Abstract
Excellent stabilization of pigmented polypropylene (PP) fiber against gas fade upon exposure to atmospheric pollutants is obtained with a hindered amine containing a polysubstituted piperazin-2-one (PSP) moiety, for example, a C.sub.2 -C.sub.12 alkylene connecting two PSP moieties, or a trisubstituted triazine ring with three PSP substituents, or a polyalkylene polyamine having pendant substituted oxo-piperazinyl-traizine moieties (PIP-T), that is, having pendant triazine rings substituted with PSP substituents. The stabilizers are unexpectedly effected when used without an antioxidant which produces yellowing, if used. Either pigmented or unpigmented PSP-stabilized PP fibers, and particularly fibers pigmented with white or pastel dyes, and having a non-alkaline "finish" are especially benefitted. Fibers made from PP stabilized with such a hindered amine, but lacking conventional antioxidants, have improved gas fade resistance, compared to fibers made from PP stabilized with several other commercially available hindered amines tested, including those which contain heterocyclic amines which are not PSPs, and especially those amines containing a hindered phenol moiety.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.