Patent · US Expired

Process for recovering boron trifluoride from an impure gaseous boron trifluoride residue

US4943423A · kind A · utility

8Cited by
9References
8Claims
0Family size

Assignee

Inventors

Key dates

Filing dateNov 29, 1988
Grant dateJul 24, 1990
Priority date
Expiry dateNov 29, 2008

Classification

  • Technology area (CPC C)Chemistry; Metallurgy
  • CPC primaryC01B35/061
  • WIPO fieldMaterials, metallurgy
  • WIPO sectorChemistry

Abstract

The present invention provides a process for recovering boron trifluoride from an impure gaseous boron trifluoride residue. The process comprises: (a) feeding an impure gaseous boron trifluoride residue containing sulfur dioxide as an impurity into a mixture of boric and sulfuric acids wherein the acid mixture absorbs boron trifluoride from the impure boron trifluoride residue and slightly absorbs or does not absorb sulfur dioxide from the impure gaseous boron trifluoride residue; and (b) removing the unabsorbed sulfur dioxide from the acid mixture. The present invention also provides a boron trifluoride preparation and purification process. The process comprises the steps of (a) reacting boric acid and fluorosulfuric acid in surfuric acid to form a product; (b) distilling the product from step (a) to yield pure boron trifluoride and impure gaseous boron trifluoride; (c) feeding the impure gaseous boron trifluoride residue containing sulfur dioxide as an impurity into a mixture of boric and sulfuric acids wherein the acid mixture absorbs boron trifluoride from the impure gaseous boron trifluoride residue and only slightly absorbs sulfur dioxide from the impure gaseous boron trifluo…

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.