Process of producing a fibrillated semi-interpenetrating polymer network of polytetrafluoroethylene and silicone elastomer and shaped products thereof
US4945125A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Jan 5, 1987 |
| Grant date | Jul 31, 1990 |
| Priority date | — |
| Expiry date | Jan 5, 2007 |
Classification
- Technology area (CPC Y)Emerging Cross-Sectional Technologies
- CPC primaryY10S264/47
- WIPO fieldMacromolecular chemistry, polymers
- WIPO sectorChemistry
Abstract
A process for producing a semi-interpenetrating polymer network of polytetrafluoroethylene and silicone elastomers is described which comprises the steps of (1) intimately blending a mixture of a major amount of unsintered and unfibrillated particulate polytetrafluoroethylene dispersion resin and minor amounts of (A) a hydrocarbon liquid and (B) an addition curable silicone composition consisting essentially of a polydiorganosiloxane having alkenyl unsaturation, an organohydrogenpoly-siloxane crosslinking agent, a catalyst for promoting crosslinking of said polysiloxane, and an inhibitor for the catalytic reaction; (2) forming said blend into an extrudable shape; (3) biaxially extruding said blend through a die into a shaped extrudate product having a randomly fibrillated structure; (4) evaporating said hydrocarbon liquid, and activating said catalyst so as to generate a cured silicone elastomer and polytetrafluoroethylene semi-interpenetrating polymer network comprising said fibrillated extrudate structure. Products produced by this process have improved physical properties as compared to extruded fibrillated polytetrafluoroethylene dispersion resin alone.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.