Selective catalytic process for controlled modification of ethylene-(alpha-olefin)-diene monomer terpolymer with halothisulfonamide
US4956420A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Sep 15, 1988 |
| Grant date | Sep 11, 1990 |
| Priority date | — |
| Expiry date | Sep 15, 2008 |
Classification
- Technology area (CPC C)Chemistry; Metallurgy
- CPC primaryC08F2810/20
- WIPO fieldMacromolecular chemistry, polymers
- WIPO sectorChemistry
Abstract
Preparation of halothio-sulfonamide-modified terpolymers having a low degree of unsaturation is accomplished by preferably reacting N-chlorothio-sulfonamide with an ethylene-(alpha-olefin)-diene monomer terpolymer comprising, for example, 1,4- hexadiene and/or dicyclopentadiene, in the presence of a catalyst of the formula MAn, where A is an anion or mixture of anions of a weak acid, and M is a metal selected from copper, antimony, bismuth and tin and n is a number which corresponds to the oxidation state of M divided by the valence of said weak acid anion. The reaction is preferably carried out in a melt phase process. Additionally, metals such as zinc and iron can be used at low concentrations in a melt phase process or at short reaction times in a solution process. Mixtures of such modified terpolymers with highly unsaturated rubbery polymers and vulcanizates of such mixtures are particularly useful in pneumatic tire sidewalls.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.