Patent · US Expired

Hollow polymer particles, process for production thereof, and use thereof as pigment

US4972000A · kind A · utility

54Cited by
21References
27Claims
0Family size

Assignee

Inventors

Key dates

Filing dateFeb 24, 1989
Grant dateNov 20, 1990
Priority date
Expiry dateFeb 24, 2009

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY10T428/2998
  • WIPO fieldMacromolecular chemistry, polymers
  • WIPO sectorChemistry

Abstract

Hollow polymer particles having at least two polymer layers, wherein (1) the particles have an average particle diameter in the range of 0.15 to 20 micrometers, (2) each of the particles has an average equivalent hollow diameter/equivalent particle diameter in the range of 0.2 to 0.8, (3) the proportion of a toluene-insoluble portion of the particles is 20 to 90% by weight, (4) the polymer particles have a melt flow rate at 180.degree. C. under 10 kgf/cm.sup.2 of 0.1 to 1 g/10 min., (5) the inside layer of the two polymer layers is composed of a crosslinked polymer and (6) the outside layer of the two polymer layers is composd of a non-crosslinked polymer. This invention also provides hollow crosslinked polymer particles wherein the proportion of a toluene-insoluble portion of the particles exceeds 85% by weight, the melt flow rate of the polymer particles at 180.degree. C. under 10 kgf/cm.sup.2 is less than 0.2 g/10 min., and the outside layer is composed of a crosslinked polymer. The hollow polymer particles are useful, for example, as a pigment, and for a paper coating composition and a general-purpose coating composition.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.