Postcuring of unsaturated stereolithographic specimens using aqueous initiating baths
US4972006A · kind A · utility
Assignee
Inventors
Key dates
| Filing date | Sep 8, 1988 |
| Grant date | Nov 20, 1990 |
| Priority date | — |
| Expiry date | Sep 8, 2008 |
Classification
- Technology area (CPC B)Performing Operations; Transporting
- CPC primaryB33Y10/00
- WIPO fieldOther special machines
- WIPO sectorMechanical engineering
Abstract
A method of curing a three-dimensional specimen of preformed cross-linked polymeric material containing polymerizable ethylenically-unsaturated material is provided in which the specimen is immersed in water having dissolved therein an amount of a water-soluble organic free-radical polymerization catalyst effective to transfer a polymerization-initiating amount of the catalyst into the preformed cross-linked polymeric material. This specimen containing the water-soluble organic free-radical polymerization catalyst is heated to a temperature causing polymerization, and is maintained at that temperature while the cure is completed. The aqueous bath preferably contains a catalyst mixture which includes a catalyst of oxidizing character in admixture with a reducing agent, such as an amine, and is maintained at a polymerization temperature of from 60.degree. C. to 100.degree. C. so that immersion of the specimen in a single bath completes the cure.
Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.