Patent · US Expired

Process for the preparation of epsilon-caprolactone

US4994583A · kind A · utility

2Cited by
6References
4Claims
0Family size

Assignee

Inventors

Key dates

Filing dateJul 12, 1989
Grant dateFeb 19, 1991
Priority date
Expiry dateJul 12, 2009

Classification

  • Technology area (CPC Y)Emerging Cross-Sectional Technologies
  • CPC primaryY02P20/582
  • WIPO fieldOrganic fine chemistry
  • WIPO sectorChemistry

Abstract

Process for manufacturing .SIGMA.- caprolactone by oxidation of cyclohexanone by means of a crude C.sub.2 -C.sub.4 percarboxylic acid solution, resulting from the reaction of hydrogen peroxide on the corresponding carboxylic acid in the presence of a weak acid catalyst, with continuous elimination of water by azeotropic entrainment, characterized in that the molar ratio of cyclohexanone used to the percarboxylic acid is between about 0.50 to 0.99.

Source: USPTO / EPO open patent data. Objective bibliographic and citation counts.